"Lawrence DčOliveiro" <_zealand> wrote in message
news:ldo-...
> In article <>, "forensic analysis" <look@me>
> wrote:
>
> >You can find an interesting technical analysis document at
> >http://www.rigakumsc.com/journal/Vol...98/wheeler.pdf
> >
> >"As iron can occur in a body centered cubic structure called alpha iron
to a
> >face centered cubic structure known as gamma iron, their properties are
> >quite different.
>
> I imagine their densities would be different as well. Face-centred cubic
> would be denser than body-centred cubic. Would the denser form also be
> the stable, lower-energy state? (That is, alpha could spontaneously turn
> into gamma.)
Well I suppose this is where we get into discussion on allotropy and phase
changes. and that's where it starts to get really interesting.
"Four changes occur in iron, which give rise to forms known as alpha, beta,
gamma and delta. Of these, a, b and d forms have the same atomic structure
(body centred cubic) while g -iron has a face centred cubic structure. Iron
can, therefore, be considered to have two allotropic modifications."
"Pure iron is one metal that changes from one of these crystalline
structures to another while remaining solid. It's BCC at temperatures up to
1,670 degrees F. But from 1,670 to 2,535 degrees F, it's FCC. Then from
2,535 to the melting temperature of 2,795 degrees F, it goes back to BCC."
Some useful online resources;
Steel structure
http://www.key-to-steel.com/Articles/Art3.htm
General phases and structures
http://www.thefabricator.com/xp/Fabr...3/03web253.xml
Detailed steel phase diagram
http://www.sv.vt.edu/classes/MSE2094...es/kimcon.html